http://thinkprogress.org/justice/2014/11/26/3596488/a-texas-lawmakers-bizarre-plan-to-secede-from-the-union-one-law-at-a-time/
"Rep. Flynn’s proposal is rooted in an unconstitutional theory known as “nullification,” which claims that a state can unilaterally declare a federal law unconstitutional and thus void within the state’s borders. The Constitution, however, explicitly provides that duly enacted federal laws “shall be the supreme law of the land; and the judges in every state shall be bound thereby, anything in the constitution or laws of any state to the contrary notwithstanding.” Thus, federal law is “supreme” over state law, and state laws that conflict with federal law — or which seek to openly defy federal law — are preempted by the federal government’s legislation."